Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature

Yasmin Akhtar

doi:doi:10.11648/j.ijsts.s.2015030102.11

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Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature

Yasmin Akhtar

Published in International Journal of Science, Technology and Society (Volume 3, Issue 1-2)

Received: 25 October 2014 Accepted: 30 October 2014 Published: 22 November 2014

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Abstract

The present experimental investigation was carried out in order to explore the possible thermodynamic and interactions studies of D(+) fructose with mixed solvent of aqueous alkali metal halides at different molalities and constant temperature . Experimental values of densities and ultrasonic velocities were carried out of the ternary mixture solution D(+)fructose with aqueous NaCl ,KCl , MgCl2 and CaCl2 under different molalities and at 303K. The related and relevant parameters correlated to the present study such as adiabatic compressibility Ks, acoustic impedance Z, apparent molal volume фv, apparent molal adiabatic compressibility, фKs, and partial molal volume ф0v and partial molal adiabatic compressibility, ф0Ks at infinite dilution. The present investigation has exploited the possible molecular associations such as ion-ion, ion-solvent, interactions in these systems. It has been observed that there exist strong solute-solvent interaction and complex formation between in these ternary systems.

Published in	International Journal of Science, Technology and Society (Volume 3, Issue 1-2) This article belongs to the Special Issue Academic Research for Multidisciplinary
DOI	10.11648/j.ijsts.s.2015030102.11
Page(s)	1-5
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

D(+)fructose, Aqueous Electrolytes, Apparent Molal Volume and Apparent Molal Adibatic Compresibility, Adiabatic Compressibility, Acoustic Impedance

References

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[3]	F. J. Millero, A. L. Surdo and C. Shiv, “Apparent molal volumes and adiabatic compressiblities of aqueous transition metals.” J. Phys. Com. Vol. 84 1980 pp 719-723.
[4]	S. S. Aswale, S.R. Aswalev and and R. S. Hajare, “Adiabatic compressibility intermolecular free length and acoustic relaxation time of aqueous antibiotic cefotaxime sodium” Indian J. Chem., vol.4 2012 pp2671-2677.
[5]	S. Thirumaran and J. K. Sabu, “Ultrasonic studies of interactions of some alkali halides in aqueous d-glucose solutions at varying molalities and temperature”, Journal Exp. Sci., Vol. 3 2012 pp 33-39.
[6]	M. J. Iqbal and M. A. Chaudhry, “ Volumetric and viscometric studies of drugs in aqueous medium at different temperature”, J. Chem. Engg. Vol. 54 2009 pp 2772-2776.
[7]	A. K. Nain and R. Pal. “ Study of solute- solute and solute -solvent interacttions of Threonine in aqueous glucose solutions at different temperatures by using volumetric ans viscometric methods”, J. Chem Thermodyn. , vol.104 2013; pp 60-98.
[8]	E. J Gonzalez, S. B. Bottini, S. Peeda and E. A. Macedo, “Liquid- Liquid equlibria of binary systems, Experimental data and Thermodynamic modeling using a group contribution equation of state” Fluid Phase Equil. Vol.362 2014 pp163-169.
[9]	M. J. Iqbal and M. Siddiquah, “ Partial molar volume of mefenamic acid in alcohol at temperature 293.15 and 313.15 K,” J. Braz. Chem. Soc. Vol.17 2006 pp727-735.
[10]	F. Ciotta, J. P. M. Truster and V. Vesovic, “ Extended hard - sphere model for the viscosity’’, Fluid Phase Equilib. Vol.363 2014 pp 239-247.
[11]	Y. Akhtar, “Volumetric and viscometric behavior of amino acids in aqueous metal electrolytes solutions at 308 K”, Fluid Phase Equil. Vol. 258 2007 pp125-131.
[12]	X. Jiang, C. Zhu and Y. Ma. “Volumetric and viscometric studies of amino acids in L-L-ascorbic acid aqueous solutions at temperature 293.15- 323.15 K”, J. Chem. Thermodyn. Vol.71 2014 pp 50-63..
[13]	R. K. Wadi and P. Ramasmi “Partial molal volumes and adiabatic compessiblities of transfer of glycine and D-L alanine from water to aqueous sodium sulphate at 288.15, 298.15 and 308.15 K”, J. Chem. Soc. Faraday Trans. Vol. 93 1997 243-247.
[14]	M. S. Hussain, T. K. Biswas, D. C. Kabiraz, M. N. Islam and M. E. Haque, “Studies on sodium dodecylsulphate in aqueous and in aqueous amino acids solutions”, J. Chem. Thermodyn. Vol.71 2014; pp 6-13.
[15]	I.L. Shulgin and E. Ruckenstein “ Relationship between preferential interac- tion of a protein in an aqueous mixed solvent and its solubility”, Biophys Chem. Vol. 118 2005 pp 128-34.
[16]	Vishnu D. , Y. Akhtar, J. D.Pandey, “Ultrasonic and Thermodynamic studies of Ternary solutions”, Acta Acoust. , Vol 84 1998 pp 976 981.

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Yasmin Akhtar. (2014). Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature. International Journal of Science, Technology and Society, 3(1-2), 1-5. https://doi.org/10.11648/j.ijsts.s.2015030102.11

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ACS Style

Yasmin Akhtar. Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature. Int. J. Sci. Technol. Soc. 2014, 3(1-2), 1-5. doi: 10.11648/j.ijsts.s.2015030102.11

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AMA Style

Yasmin Akhtar. Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature. Int J Sci Technol Soc. 2014;3(1-2):1-5. doi: 10.11648/j.ijsts.s.2015030102.11

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@article{10.11648/j.ijsts.s.2015030102.11,
  author = {Yasmin Akhtar},
  title = {Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature},
  journal = {International Journal of Science, Technology and Society},
  volume = {3},
  number = {1-2},
  pages = {1-5},
  doi = {10.11648/j.ijsts.s.2015030102.11},
  url = {https://doi.org/10.11648/j.ijsts.s.2015030102.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijsts.s.2015030102.11},
  abstract = {The present experimental investigation was carried out in order to explore the possible thermodynamic and interactions studies of D(+) fructose with mixed solvent of  aqueous alkali metal halides at different molalities and constant temperature . Experimental values of densities and ultrasonic velocities were carried out of the ternary mixture solution D(+)fructose with aqueous NaCl ,KCl , MgCl2 and CaCl2 under different molalities and at 303K. The related and relevant parameters correlated to the present study such as   adiabatic compressibility Ks, acoustic impedance Z, apparent molal volume фv, apparent molal adiabatic compressibility, фKs, and partial molal volume ф0v and partial molal adiabatic compressibility, ф0Ks at infinite dilution. The present investigation has exploited the possible molecular associations such as ion-ion,  ion-solvent,  interactions in these systems. It has been observed that there exist strong solute-solvent interaction and complex formation between in these ternary systems.},
 year = {2014}
}

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TY  - JOUR
T1  - Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature
AU  - Yasmin Akhtar
Y1  - 2014/11/22
PY  - 2014
N1  - https://doi.org/10.11648/j.ijsts.s.2015030102.11
DO  - 10.11648/j.ijsts.s.2015030102.11
T2  - International Journal of Science, Technology and Society
JF  - International Journal of Science, Technology and Society
JO  - International Journal of Science, Technology and Society
SP  - 1
EP  - 5
PB  - Science Publishing Group
SN  - 2330-7420
UR  - https://doi.org/10.11648/j.ijsts.s.2015030102.11
AB  - The present experimental investigation was carried out in order to explore the possible thermodynamic and interactions studies of D(+) fructose with mixed solvent of  aqueous alkali metal halides at different molalities and constant temperature . Experimental values of densities and ultrasonic velocities were carried out of the ternary mixture solution D(+)fructose with aqueous NaCl ,KCl , MgCl2 and CaCl2 under different molalities and at 303K. The related and relevant parameters correlated to the present study such as   adiabatic compressibility Ks, acoustic impedance Z, apparent molal volume фv, apparent molal adiabatic compressibility, фKs, and partial molal volume ф0v and partial molal adiabatic compressibility, ф0Ks at infinite dilution. The present investigation has exploited the possible molecular associations such as ion-ion,  ion-solvent,  interactions in these systems. It has been observed that there exist strong solute-solvent interaction and complex formation between in these ternary systems.
VL  - 3
IS  - 1-2
ER  -

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Author Information

Yasmin Akhtar

Department of Chemistry, University of Tabuk, Tabuk, Saudi Arabia

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APA Style

Yasmin Akhtar. (2014). Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature. International Journal of Science, Technology and Society, 3(1-2), 1-5. https://doi.org/10.11648/j.ijsts.s.2015030102.11

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ACS Style

Yasmin Akhtar. Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature. Int. J. Sci. Technol. Soc. 2014, 3(1-2), 1-5. doi: 10.11648/j.ijsts.s.2015030102.11

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AMA Style

Yasmin Akhtar. Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature. Int J Sci Technol Soc. 2014;3(1-2):1-5. doi: 10.11648/j.ijsts.s.2015030102.11

Copy | Download

@article{10.11648/j.ijsts.s.2015030102.11,
  author = {Yasmin Akhtar},
  title = {Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature},
  journal = {International Journal of Science, Technology and Society},
  volume = {3},
  number = {1-2},
  pages = {1-5},
  doi = {10.11648/j.ijsts.s.2015030102.11},
  url = {https://doi.org/10.11648/j.ijsts.s.2015030102.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijsts.s.2015030102.11},
  abstract = {The present experimental investigation was carried out in order to explore the possible thermodynamic and interactions studies of D(+) fructose with mixed solvent of  aqueous alkali metal halides at different molalities and constant temperature . Experimental values of densities and ultrasonic velocities were carried out of the ternary mixture solution D(+)fructose with aqueous NaCl ,KCl , MgCl2 and CaCl2 under different molalities and at 303K. The related and relevant parameters correlated to the present study such as   adiabatic compressibility Ks, acoustic impedance Z, apparent molal volume фv, apparent molal adiabatic compressibility, фKs, and partial molal volume ф0v and partial molal adiabatic compressibility, ф0Ks at infinite dilution. The present investigation has exploited the possible molecular associations such as ion-ion,  ion-solvent,  interactions in these systems. It has been observed that there exist strong solute-solvent interaction and complex formation between in these ternary systems.},
 year = {2014}
}

Copy | Download

TY  - JOUR
T1  - Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature
AU  - Yasmin Akhtar
Y1  - 2014/11/22
PY  - 2014
N1  - https://doi.org/10.11648/j.ijsts.s.2015030102.11
DO  - 10.11648/j.ijsts.s.2015030102.11
T2  - International Journal of Science, Technology and Society
JF  - International Journal of Science, Technology and Society
JO  - International Journal of Science, Technology and Society
SP  - 1
EP  - 5
PB  - Science Publishing Group
SN  - 2330-7420
UR  - https://doi.org/10.11648/j.ijsts.s.2015030102.11
AB  - The present experimental investigation was carried out in order to explore the possible thermodynamic and interactions studies of D(+) fructose with mixed solvent of  aqueous alkali metal halides at different molalities and constant temperature . Experimental values of densities and ultrasonic velocities were carried out of the ternary mixture solution D(+)fructose with aqueous NaCl ,KCl , MgCl2 and CaCl2 under different molalities and at 303K. The related and relevant parameters correlated to the present study such as   adiabatic compressibility Ks, acoustic impedance Z, apparent molal volume фv, apparent molal adiabatic compressibility, фKs, and partial molal volume ф0v and partial molal adiabatic compressibility, ф0Ks at infinite dilution. The present investigation has exploited the possible molecular associations such as ion-ion,  ion-solvent,  interactions in these systems. It has been observed that there exist strong solute-solvent interaction and complex formation between in these ternary systems.
VL  - 3
IS  - 1-2
ER  -

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